Don't know if this is still an interesting topic to anyone; but I had a few things to add. My general setup proc gear includes the Buckler, Boner Girdle, Invoker Earring (noob, I know), MO hat, and the Wip from sawtooth (melee proc); and of all of them Direwood Thorns ends up doing the most damage total. I also checked and I do think that even tho 2 of my procs say they do piercing damage, they are based on my spell crits.
I have 38.5% spell crits in the group I'm always in, and my parser showed the following crit rates for my proccing gear
Direwood Thorns 38%
Char 45%
Burning Affliction 45%
Strike of Thorns 50% (Might be slightly off because it is an AE proc, so a crit on an encounter of 3 will bonk this up a bit)
Mutagenic Haze 47%
I stopped using the Fitzpizzle Protector because I got that Censer of Planar energy to help with power and general stats, and because the protector was always the lowest of all my proc gear for some reason, <1% of my dps.
In my opinion, at this time, the Buckler is pretty good. I do not have the blood of the brood watcher to compare tho
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i havent even pointed out the fact that i can 1% spell crit both fitz and blood but not the direwood, so its looking pretty bleak for the buckler at this point.
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This was primarily what I was responding to, but I might be missinterpreting what you meant, I'm not sure
edit: more spelling errors because I don't proof read before submitting